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Beilstein J. Org. Chem. 2015, 11, 1902–1909, doi:10.3762/bjoc.11.205
Graphical Abstract
Figure 1: Some spacial and electronic mimetics with fluorine as a design feature [3-6].
Figure 2: α-Fluorovinyl thioesters offer prospects as thioester enol/ate mimetics [7].
Scheme 1: HF·Py mediated hydrofluorinations of 1a.
Scheme 2: BF3·Et2O/3HF·Et3N mediated hydrofluorination of 1a.
Scheme 3: Proposed Lewis acid-mediated hydroflurination of sulfides 1.